AUTOMOBILE ENGINE COOLANT RELATED FIRES
By
Charles C. Roberts, Jr., Ph. D., P.E.
Automobile engine coolant related fires may result from engine 
coolant leakage, an increase in the concentration of the glycol in 
the water/glycol mixture, the nature of the vapor/particle 
distribution, and contact with an ignition source in the engine 
compartment. Ethylene glycol, a common coolant, is a flammable 
liquid with an ignition temperature near 800F. In recent years, 
propylene glycol is being used because of environmental reasons. 
Propylene glycol is also a flammable liquid with an ignition 
temperature near 700F. In an automotive application, the glycol is 
mixed with water at about a 50/50 ratio. Ignition of this 
concentration of coolant is difficult because of the water. When 
released at high temperatures into the atmosphere where the water 
evaporates, the glycol vapor/liquid droplets can reach the state of 
an ignitable mixture. Typical ignition sources in the engine 
compartment include hot surfaces (exhaust manifold, exhaust 
system) and electrical components (relays, distributor, spark plug 
wires). Automobile accidents, resulting in hot vapor expulsion 
from the coolant system, are also known to cause fires.
Figure 1
Figure 1 is a view of a late model sedan that was being driven 
home from a radiator shop where the radiator had been repaired. 
The repair entailed draining and replacing the coolant. After 
driving several miles, the owner of the vehicle noticed smoke 
under the hood. The vehicle was stopped and a fire ensued in the 
engine compartment. Burn patterns in Figure 1 confirmed the 
engine compartment origin of the fire.  
Figure 2
Figure 2 is a closer view of the engine compartment with the hood 
raised. Inspection revealed an open engine coolant system cap as 
indicated by the arrow in Figure 2 and shown in detail in Figure 3. 
Apparently, the radiator coolant system cap was not found secured to
the flange assembly.
Figure 3
Figure 4 shows an exemplar cap constructed of steel. The cap has a 
locking feature, which keeps it in place and reduces the chance of 
accidental removal when the coolant is hot. Because of the steel 
construction, such a cap would not be consumed in a fire of this 
magnitude and should have remained in place.
Figure 4
The absence of the cap suggests that the radiator repair shop did 
not properly secure it to the cooling system flange assembly. This 
results in heating of the coolant with no pressure in the system. 
Water will boil first at about 212 F, while the glycol will not boil 
off until about 370 F. Once the water had boiled away and the 
glycol coolant was expelled from the open flange, it was ignited by 
several possible ignition sources in the engine compartment and 
resulted in the coolant related fire. 
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